Application of DMCHA as a high-efficiency catalyst in elastomers

March 10, 2025by admin0

The application of DMCHA as a high-efficiency catalyst in elastomers

Introduction

Elastomers are a type of polymer materials with high elasticity and reversible deformation capabilities, and are widely used in automobiles, construction, electronics, medical and other fields. With the advancement of science and technology, the performance requirements of elastomers are becoming higher and higher, especially in terms of heat resistance, aging resistance, mechanical strength, etc. To meet these needs, catalysts play a crucial role in the synthesis and processing of elastomers. DMCHA (N,N-dimethylcyclohexylamine) has been widely used in the field of elastomers in recent years. This article will introduce in detail the characteristics, mechanism of action, application fields and specific application cases in elastomers.

1. Basic characteristics of DMCHA

1.1 Chemical structure

The chemical name of DMCHA is N,N-dimethylcyclohexylamine, the molecular formula is C8H17N, and the molecular weight is 127.23 g/mol. The structure is as follows:

 CH3
       |
  N-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2
       |
      CH3

1.2 Physical Properties

Properties	value
Appearance	Colorless to light yellow liquid
Density (20°C)	0.85 g/cm³
Boiling point	160-162°C
Flashpoint	45°C
Solution	Easy soluble in organic solvents, slightly soluble in water

1.3 Chemical Properties

DMCHA is a strong basic organic amine with high reactivity. It is able to react with a variety of organic and inorganic compounds, especially in catalytic reactions. The alkalinity of DMCHA makes it play an important role in the synthesis of materials such as polyurethane and epoxy resin.

2. The mechanism of action of DMCHA

2.1 Catalytic mechanism

DMCHA, as a highly efficient catalyst, mainly plays a role through the following two mechanisms:

Basic Catalysis: The strong alkalinity of DMCHA allows it to accelerate certain chemical reactions, especially in the synthesis of polyurethanes and epoxy resins. DMCHA can promote the reaction of isocyanate with alcohols or amines, thereby accelerating the polymerization process.
Nucleophilic Catalysis: DMCHA contains lone pairs of electrons on its nitrogen atom, which can act as a nucleophilic reagent to attack the electrophilic potential in the reactants, thereby accelerating the reaction process.

2.2 Catalytic efficiency

The catalytic efficiency of DMCHA is closely related to its molecular structure. Its cyclohexyl structure provides good steric hindrance effect, making DMCHA highly selective in reaction. In addition, moderate alkalinity of DMCHA will not lead to excessive rapid reaction and out of control, nor will it affect the reaction rate due to weak alkalinity.

III. Application of DMCHA in elastomers

3.1 Polyurethane elastomer

Polyurethane elastomers are an important class of elastic materials and are widely used in automobiles, construction, electronics and other fields. DMCHA is mainly used as a catalyst in the synthesis of polyurethane elastomers, which can significantly improve the reaction rate and product performance.

3.1.1 Reaction process

In the synthesis of polyurethane elastomers, DMCHA mainly catalyzes the reaction of isocyanate with polyols. The reaction process is as follows:

Prepolymerization reaction: Isocyanate and polyol form prepolymers under the catalysis of DMCHA.
Chain extension reaction: The prepolymer and chain extender (such as diamine or diol) are further reacted under the catalysis of DMCHA to form a high molecular weight polyurethane elastomer.

3.1.2 Application Cases

Application Fields	Specific application	DMCHA dosage (wt%)	Performance improvement effect
Auto Industry	Car seats, steering wheel, shock absorbers	0.1-0.5	Improve the mechanical strength and heat resistance of the elastomer
Construction Industry	Waterproof coatings, sealants	0.2-0.8	Improve the adhesion and weather resistance of the paint
Electronics Industry	Cable sheath, insulation material	0.1-0.3	Improve the insulation properties and aging resistance of materials

3.2 Epoxy resin elastomer

Epoxy resin elastomers are a type of materials with excellent mechanical properties and chemical resistance, and are widely used in aerospace, electronics, construction and other fields. DMCHA is mainly used as a curing agent in the synthesis of epoxy resin elastomers, which can significantly improve the curing rate and product performance.

3.2.1 Reaction process

In the synthesis of epoxy resin elastomers, DMCHA mainly catalyzes the reaction of epoxy groups with amine-based curing agents. The reaction process is as follows:

Ring opening reaction: The epoxy group undergoes a ring opening reaction with an amine curing agent under the catalysis of DMCHA to form a hydroxyl group.
Crosslinking reaction: The generated hydroxyl group further reacts with epoxy groups to form a three-dimensional crosslinking network structure.

3.2.2 Application Cases

Application Fields	Specific application	DMCHA dosage (wt%)	Performance improvement effect
Aerospace	Composite materials, structural glue	0.5-1.0	Improve the mechanical strength and heat resistance of the material
Electronics Industry	Encapsulation materials, insulation materials	0.3-0.8	Improve the insulation properties and aging resistance of materials
Construction Industry	Floor coatings, anticorrosion coatings	0.2-0.6	Improve the adhesion and weather resistance of the paint

3.3 Silicone rubber elastomer

Silicone rubber elastomer is a type of material with excellent heat resistance, weather resistance and electrical insulation, and is widely used in electronics, medical, automobiles and other fields. DMCHA is mainly used as a catalyst in the synthesis of silicone rubber elastomers, which can significantly improve the reaction rate and product performance.

3.3.1 Reaction process

In the synthesis of silicone rubber elastomers, DMCHA mainly catalyzes the silicon hydrogen addition reaction. The reaction process is as follows:

Silicone addition reaction: hydrogen-containing silicone oil and BAlkenyl silicone oil undergoes a hydrogen silicon addition reaction under the catalysis of DMCHA to form a silicone rubber elastomer.
Crosslinking reaction: The generated silicone rubber elastomer is further cross-linked to form a three-dimensional network structure.

3.3.2 Application Cases

Application Fields	Specific application	DMCHA dosage (wt%)	Performance improvement effect
Electronics Industry	Cable sheath, insulation material	0.1-0.3	Improve the insulation properties and aging resistance of materials
Medical Industry	Medical catheters, seals	0.2-0.5	Improve the biocompatibility and heat resistance of the material
Auto Industry	Seals, Shock Absorbers	0.1-0.4	Improve the mechanical strength and weather resistance of the material

IV. Application advantages of DMCHA

4.1 Efficiency

DMCHA, as a highly efficient catalyst, can significantly increase the reaction rate, shorten the production cycle, and thus improve production efficiency.

4.2 Selectivity

The molecular structure of DMCHA provides a good steric hindrance effect, making it highly selective in the reaction, can effectively control the reaction process, and reduce the occurrence of side reactions.

4.3 Stability

DMCHA can maintain high catalytic activity under high temperature and high pressure conditions, has good thermal stability and chemical stability, and is suitable for a variety of complex reaction environments.

4.4 Environmental protection

DMCHA is an organic amine catalyst with low toxicity and volatileness, environmentally friendly and meets the environmental protection requirements of modern industry.

V. Application prospects of DMCHA

With the widespread application of elastomer materials in multiple fields, the demand for catalysts is also increasing. As a catalyst with high efficiency, good selectivity and high stability, DMCHA has broad application prospects. In the future, with the advancement of science and technology and the improvement of processes, DMCHA will be more widely used in elastomers and its performance will be further improved.

5.1 Development of new elastomers

With new material technologyWith the continuous development of new elastomers, the development of new elastomers will become an important direction in the future. As a highly efficient catalyst, DMCHA will play an important role in the synthesis of new elastomers and promote the performance improvement and application expansion of elastomer materials.

5.2 Green and environmentally friendly technology

With the increase in environmental awareness, green environmental protection technology will become an important trend in future industrial development. As an environmentally friendly catalyst, DMCHA will play an important role in the synthesis of green elastomer materials and promote the sustainable development of elastomer materials.

5.3 Intelligent production

With the development of intelligent manufacturing technology, the production of elastomer materials will be more intelligent and automated. As a highly efficient catalyst, DMCHA will play an important role in intelligent production and improve production efficiency and product quality.

VI. Conclusion

DMCHA, as a highly efficient catalyst, plays an important role in the synthesis and processing of elastomer materials. Its high efficiency, selectivity, stability and environmental protection make it widely used in elastomeric materials such as polyurethane, epoxy resin, silicone rubber. With the advancement of science and technology and the improvement of process, DMCHA will be more widely used in elastomers and its performance will be further improved, providing strong support for the development of elastomer materials.

Appendix: DMCHA product parameter table

parameters	value
Appearance	Colorless to light yellow liquid
Density (20°C)	0.85 g/cm³
Boiling point	160-162°C
Flashpoint	45°C
Solution	Easy soluble in organic solvents, slightly soluble in water
Molecular Weight	127.23 g/mol
Molecular formula	C8H17N
Storage Conditions	Cool, dry, ventilated
Packaging Specifications	25kg/barrel, 200kg/barrel
Shelf life	12 months

Note: The content of this article is for reference only, and the specific application needs to be adjusted according to actual conditions.