IEC 63026 partial discharge control of 1-methylimidazole catalyst in superconducting cable insulation layer

March 19, 2025by admin0

1. Preface: The “guardian” of superconducting cables – 1-methylimidazole catalyst

In today’s era of increasing demand for electricity, superconducting cables, as the “black technology” in the field of power transmission, are changing our lives at an unprecedented speed. It not only has amazing current carrying capacity, but also achieves ultra-low loss power transmission, making it the “superhero” of modern power grids. However, behind this shining halo, there is an easily overlooked but crucial issue – the phenomenon of partial discharge. This is like a “time bomb” lurking in the insulation of superconducting cables. Once it gets out of control, it may cause serious equipment failures and economic losses.

To solve this difficult problem, scientists have turned their attention to a magical chemical, 1-methylimidazole catalyst. This seemingly ordinary compound has the magic of “renewing” the properties of insulating materials. Through clever combination with insulating materials such as epoxy resin, it can significantly improve the material’s corona resistance and local discharge resistance, just like putting an indestructible “protective armor” on superconducting cables.

This article will lead readers to gain insight into the application of 1-methylimidazole catalysts in superconducting cable insulation layers, especially its outstanding performance in local discharge control under the IEC 63026 standard. We will start from the basic characteristics of the catalyst and gradually explore its action mechanism, performance advantages and practical application effects, and conduct detailed analysis based on new research results at home and abroad. In addition, we will also demonstrate through specific cases and experimental data how this catalyst can help superconducting cables break through performance bottlenecks and become an indispensable key technology in future power grid construction.

In order to make the article more readable, we will adopt a simple and easy-to-understand language style, appropriately use metaphor and rhetorical techniques, and strive to make complex scientific principles vivid and interesting. At the same time, the article will also be interspersed with rich tables and literature citations to provide readers with comprehensive and authoritative information support. Let us walk into this charming technological world together and unveil the mystery of 1-methylimidazole catalyst.

2. Basic characteristics of 1-methylimidazole catalyst

To understand the important role of 1-methylimidazole catalyst in superconducting cable insulation layer, we must first understand the basic attributes of this “behind the scenes”. 1-Methylimidazole (1-Methylimidazole), referred to as MI, is an organic compound with an aromatic ring structure, with a molecular formula of C4H6N2. Its molecular weight is only 82.10 g/mol, and it looks like a colorless to light yellow liquid, with a boiling point of about 115°C and a melting point below -50°C. It has a low viscosity and good fluidity. These physical properties allow MI to be evenly distributed during the processing of insulating materials, ensuring efficient catalytic reactions.

From the chemical nature, the large 1-methylimidazole is characterized by its unique biazole heterocyclic structure. This structure gives MI a powerfulBasicity and polarity enable them to effectively activate epoxy groups and promote the occurrence of cross-linking reactions. It is more worth mentioning that the molecular structure of MI also contains a reactive methyl substituent, which not only enhances its catalytic activity, but also gives it excellent compatibility and dispersion. This characteristic is crucial to improving the overall performance of insulating materials.

To better understand the properties of MI, we can compare it with other common catalysts. The following table summarizes the main performance parameters of 1-methylimidazole and several typical epoxy curing agents:

Parameter indicator	1-methylimidazole	Triethylamine	Dibutyltin dilaurate	Phenol curing agent
Molecular Weight	82.10 g/mol	101.19 g/mol	475.02 g/mol	94.11 g/mol
Boiling point (°C)	115	89	300	181
Strength of alkalinity	Strong	Strong	Medium	Weak
Polarity size	High	Higher	Low	Medium
Compatibility	Outstanding	Good	Poor	General

From the table above, it can be seen that 1-methylimidazole has obvious advantages in multiple key performance indicators. Especially in terms of compatibility and polarity, MI is particularly outstanding. This superiority is derived from its special molecular structure, where the two nitrogen atoms on the imidazole ring provide strong alkalinity, while the methyl substituent enhances the hydrophobicity of the molecule, allowing it to maintain good dispersion in both organic solvents and polymer systems.

In addition, MI has some other features worth paying attention to. For example, it has low volatility at room temperature and is not prone to irritating odors; it has good thermal stability and does not significantly decompose below 150°C; and it has good compatibility with various epoxy resin systems, which can effectively adjust the curing reaction rate. These characteristics together determine the wide application value of MI in superconducting cable insulation materials.

III. The mechanism of action of 1-methylimidazole catalyst

To deeply understand the mechanism of action of 1-methylimidazole catalysts in the insulating layer of superconducting cables, we need to analyze their working principle from a microscopic level. Simply put, 1-methylimidazole achieves precise regulation of the curing process of epoxy resin through its unique molecular structure and chemical properties. This regulatory effect is mainly reflected in the following aspects:

First is the activation process of epoxy groups. When 1-methylimidazole comes into contact with the epoxy resin, the nitrogen atoms on its imidazole ring preferentially form coordination bonds with the oxygen atoms in the epoxy group. This coordination reduces the electron cloud density of the epoxy group and makes it more susceptible to attack by nucleophiles. In layman’s terms, this is like installing a “code lock” on the epoxy group that originally “closed the door”. Only 1-methylimidazole holding the correct “key” can open the door and start the subsequent cross-linking reaction.

The next is the construction stage of the cross-link network. Under the catalysis of 1-methylimidazole, the epoxy group undergoes a ring-opening reaction with a curing agent (such as polyols or amine compounds) to form hydroxyl and ether bonds. As the reaction continues, these newly formed functional groups will further participate in the reaction, eventually forming a three-dimensional crosslinking network structure. This process is similar to the construction workers building the house frame according to drawings, and each reaction step is an important part of the overall structural integrity.

It is particularly noteworthy that 1-methylimidazole plays multiple roles throughout the reaction. In addition to basic catalytic functions, it can also interact with other molecules in the crosslinking network through hydrogen bonding and van der Waals forces, enhancing the stability and density of the overall structure. This synergy is like a well-trained band where each member plays his own part while maintaining perfect harmony with the rest of the members.

To show this process more intuitively, we can refer to the results of the research by Kumar et al. (2019). Through infrared spectroscopy, they found that after the addition of 1-methylimidazole, the characteristic absorption peak of epoxy groups rapidly weakened within 10 minutes, indicating that the curing reaction rate was significantly improved. At the same time, differential scanning calorimetry (DSC) tests showed that the addition of MI reduced the starting temperature of the curing reaction by about 15°C, indicating that it did play an effective catalytic role.

Another important finding comes from the Dynamic Mechanical Analysis (DMA) study by Zhang et al. (2020). They observed that in epoxy systems containing 1-methylimidazole, the glass transition temperature (Tg) increased by about 10°C, which directly reflects the increase in crosslinking network density. At the same time, the maintenance time of the energy storage modulus in the high-temperature area was also significantly extended, indicating that the thermomechanical properties of the material have been significantly improved.

In addition, Wang et al. (2021) used scanning electron microscopy (SEM) to introduce the micromorphology of the cured productCharacterized. The results showed that the samples catalyzed with MI showed a more uniform and dense microstructure with a drop in porosity by about 30%. This structural feature is particularly important for suppressing local discharge phenomena, as any minor defect can become the concentration point of the electric field, which in turn causes breakdown.

IV. Performance advantages of 1-methylimidazole catalyst

When we explore in-depth the application of 1-methylimidazole catalyst in superconducting cable insulation, its unique advantages appear like bright stars. The first thing to bear is its excellent catalytic efficiency. According to research data from Li et al. (2018), 1-methylimidazole can achieve the same curing effect at a lower dose compared to traditional amine catalysts. Specifically, under the same conditions, MI only needs 60% of the conventional catalyst dosage to achieve the optimal curing state. This efficiency not only reduces production costs, but also reduces potential problems caused by excessive catalyst residues.

The second is its significant improvement in electrical performance of insulating materials. Yang et al. (2019) found through a series of dielectric tests that the breakdown strength of epoxy systems catalyzed using MI has increased by about 25% and the volume resistivity has increased by nearly an order of magnitude. This improvement is mainly due to the ability of MI to promote the formation of a denser crosslinking network structure, thereby effectively inhibiting the growth of electrical branches and local discharge. Just like a strong line of defense, keeping possible electrical failures out.

More importantly, the 1-methylimidazole catalyst also exhibits excellent thermal stability and aging resistance. Long-term aging experiments by Chen et al. (2020) showed that after continuous operation at 150°C for 1000 hours, MI-catalyzed samples could still maintain more than 90% of the initial performance. In contrast, samples with traditional curing agents decreased by more than 40%. This durability is undoubtedly a huge advantage for equipment such as superconducting cables that require long-term and stable operation.

In order to show these advantages more intuitively, we can refer to the following experimental data comparison:

Performance metrics	MI catalytic system	Traditional system	Elevation
Breakdown Strength (kV/mm)	25	20	+25%
Volume resistivity (Ω·cm)	1×10^16	1×10^15	+10 times
Glass transition temperature (°C)	150	140	+7%
Aging resistance (%)	>90	<60	Sharp improvement

These data fully demonstrate the great potential of 1-methylimidazole catalysts in improving the performance of superconducting cable insulation layers. It not only solves many problems existing in traditional catalysts, but also provides a new direction for the development of higher performance insulation materials. Just like a master key, it opens the door to high-performance insulation.

V. Practical application effects of 1-methylimidazole catalyst

In practical engineering applications, the effect of 1-methylimidazole catalyst has been fully verified. Take a large superconducting cable manufacturer as an example. They use an MI-catalytic epoxy system in the insulating layer of the new generation of high-voltage DC cables. After two years of actual operational testing, the product’s partial discharge control performance under the IEC 63026 standard is impressive.

First, in terms of local discharge starting voltage (PDIV), the cable using the MI catalytic system reaches 12 kV/mm, which is much higher than the 8 kV/mm of the traditional system. This means that the cable maintains stable electrical performance even under extreme conditions. At the same time, long-term operation data show that after 1,000 hours of accelerated aging test, the PDIV value of the MI system has dropped by only 5%, while the traditional system has dropped by nearly 30%.

In terms of corona resistance, the MI catalytic system also performs well. Experimental records show that after continuous operation at an electric field intensity of 8 kV/mm for 1000 hours, the surface erosion depth of the MI system was only 0.02 mm, while the traditional system reached 0.15 mm. This significant difference is mainly attributed to the fact that MI promotes the formation of a denser crosslinking network structure, effectively inhibiting material degradation caused by corona discharge.

To display these effects more intuitively, we can refer to the following actual test data:

Test items	MI catalytic system	Traditional system	Improvement
Particular discharge start voltage (kV/mm)	12	8	+50%
Surface erosion depth (mm/1000h)	0.02	0.15	-87%
Insulation life (h@150°C)	>10,000	<5,000	Sharp improvement
Production efficiency (kg/h)	50	30	+67%

It is particularly worth mentioning that the MI catalytic system also brings significant economic benefits. Due to its higher catalytic efficiency, the amount of catalyst required per unit yield is reduced by 40%, while the curing cycle is reduced by about 30%. These factors work together to reduce the production cost per meter of cable by about 15%. This is undoubtedly an attractive advantage for large-scale manufacturing companies.

In addition, the MI catalytic system also demonstrates good environmental friendliness. Research shows that the emission of volatile organic compounds (VOC) produced during its production process is more than 60% lower than that of traditional systems, and meets increasingly stringent environmental protection requirements. This green feature makes MI an ideal choice for the future development of superconducting cables.

VI. Current status and development trends of domestic and foreign research

Around the world, research on the application of 1-methylimidazole catalysts in superconducting cable insulation layers is booming. Foreign research institutions generally pay attention to their performance under extreme conditions. For example, the Oak Ridge National Laboratory (ORNL) in recent years has focused on the catalytic behavior of MI in liquid nitrogen environment (77 K). Their research shows that under low temperature conditions, MI can still maintain good catalytic activity, and the stability of its crosslinking network structure is increased by about 20% compared with normal temperature. This characteristic is of great significance for the application of low-temperature superconducting cables.

In contrast, domestic research focuses more on large-scale production and cost control of MI catalytic systems. A study from the School of Materials at Tsinghua University shows that by optimizing the synthesis process, the production cost of MI can be reduced by about 30%, while keeping its performance unaffected. This research result has been successfully applied to many cable manufacturing companies, significantly enhancing the market competitiveness of domestic superconducting cables.

It is worth noting that the International Organization for Standardization (ISO) is developing new testing methods to more accurately evaluate the long-term stability of MI catalytic systems. According to preliminary test results from the Japan Institute of Industrial Technology (AIST), after 10 hot and cold cycles (-196°C to 150°C), the MI catalytic system has a decrease of less than 5%, showing excellent environmental adaptability.

An important trend in the current study is the use of MI in combination with other functional additives to further enhance the overall performance of insulating materials. A study by the Fraunhofer Association in Germany showed that by introducing nanofillers into the MI system, breakdown strength can be increased by about 30% without sacrificing flexibility. This composite modification technology is expected to become the insulating material of superconducting cables in the futureThe mainstream direction of development.

In addition, the development of intelligent monitoring technology has also opened up new ways for the application of MI catalytic systems. The University of Cambridge in the UK has developed an online monitoring system based on fiber optic sensing, which can monitor the curing degree and local discharge status of the MI catalytic system in real time. The successful application of this technology has made the production process of superconducting cables more controllable and the product quality is more guaranteed.

Looking forward, with the advancement of global energy Internet construction, the demand for superconducting cables will continue to grow, which will promote the continuous innovation and development of MI catalytic technology. It is estimated that by 2030, the market share of superconducting cables using MI catalytic systems will reach more than 60%, becoming an important pillar technology in the field of high-end power transmission.

7. Conclusion and Outlook: Bright Prospects of 1-methylimidazole Catalyst

Reviewing the full text, the 1-methylimidazole catalyst has shown an unparalleled advantage in the local discharge control of the superconducting cable insulation layer with its unique molecular structure and excellent catalytic properties. From basic theory to practical applications, from performance improvement to economic benefits, MI has drawn an exciting technical blueprint for us. Just like an excellent conductor, MI cleverly coordinates the various components in the epoxy resin system and plays a gorgeous movement of high-performance insulation.

Looking forward, with the acceleration of the global energy interconnection process, superconducting cables will play an increasingly important role in the construction of smart grids. As one of its core components, the insulating layer will continue to rely on innovative technologies such as 1-methylimidazole to achieve performance breakthroughs. It can be foreseen that in the near future, the MI catalytic system will not only be limited to existing application scenarios, but will develop towards multifunctional and intelligent directions, bringing revolutionary changes to superconducting cable technology.

After, let us end this article with a philosophical saying: “Real innovation is not to subvert the past, but to see further on the shoulders of giants.” 1-methylimidazole catalyst is such an innovative achievement that stands at the forefront of the times. It not only inherits the advantages of traditional technology, but also creates a new development space through its own unique advantages. I believe that in the near future, this technology will make greater contributions to the sustainable development of human society.

References

[1] Kumar, A., et al. (2019). “Effect of 1-Methylimidazole on Epoxy Curing Kinetics.” Journal of Applied Polymer Science, Vol. 136, No. 15.

[2] Zhang, L., et al. (2020). “Dynamic Mechanical Analysis of Epoxy Systems with 1-Methylimidazole Catalyst.” Polymer Testing, Vol. 83.

[3] Wang, X., et al. (2021). “Microstructure Characterization of Epoxy Resin Cured with 1-Methylimidazole.” Materials Chemistry and Physics, Vol. 257.

[4] Li, J., et al. (2018). “Catalytic Efficiency of 1-Methylimidazole in Epoxy Systems.” European Polymer Journal, Vol. 106.

[5] Yang, H., et al. (2019). “Electrical Properties Improvement by 1-Methylimidazole Catalyst.” IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 26, No. 3.

[6] Chen, W., et al. (2020). “Thermal Stability Study of Epoxy Resins with 1-Methylimidazole.” Journal of Thermal Analysis and Calorimetry, Vol. 139, No. 3.